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However, in the second set, Ivanovic broke Williams twice including in the ninth game to take the set.In the final set, Ivanovic broke Williams to love in the second game and that was enough to close out the match in the ninth game.Williams broke in the fifth game of the second set and held the break to served it out in the tenth game.Williams made 35 winners including 11 aces and 36 unforced errors in the match.
It was also Williams' first loss to Ivanovic, having won their four previous meetings in straight sets and losing no more than four games in each set.
She broke Barty twice in the first set and served it out in the eighth game.
In the second set, Williams broke Barty three times, including in the final game in the seventh game of the second to close it out in just under an hour.
She was coming off a 22 match winning streak that stretches from the 2012 US Open.
In the first round she faced wildcard Ashleigh Barty.